Seminars

Seminars are held Wednesdays, at 3:30 pm, in person, at Seaver Science Library, Room 202 (SSL 202) and/or as Zoom webinars. See the individual seminar announcements for details.

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Keynote Lecture Series Archive

Fall, 2025

Electrokinetic Phenomena in Nanoconfinement: From Molecular Structure to Flow Control

Thomas Petersen

Assistant Porfessor
Sonny Astani Department of Civil and Environmental Engineering
University of Southern California
Los Angeles, CA

This seminar investigates electrokinetic phenomena in nanoscale confinement. I first explore how surface charge patterning and geometric undulations control flow in corrugated, charge-patterned nanochannels. Performing fully nonlinear Poisson-Nernst-Planck-Stokes (PNPS) simulations, I demonstrate three flow regimes—surface-gradient-induced electroosmosis, electrokinetically inhibited flow, and pressure-dominated flow—and show how charge placement and Debye screening enable selective ionic current control for envisioned applications of desalination and energy harvesting. As the PNPS equations are performed on continuum concentration fields, much detail about the molecular interactions between water molecules and co- and counter-ions is omitted in the formulation.

To address this limitation, I present a classical density functional theory (cDFT) framework. By explicitly including excluded volume effects, hydrogen bonding between water molecules, dispersion interactions, and electrostatic correlations, the model reproduces experimental observations of molecular layering near graphene and mica surfaces. The framework reveals how ion-specific properties and surface texture govern the electric double layer organization and demonstrates that multivalent ions generate attractive stresses between like-charged surfaces through out-of-plane structuring.

Thomas Petersen, Assistant Professor in USC's Sonny Astani Department of Civil and Environmental EngineeringThomas Petersen started working as an Assistant Professor in the Sonny Astani Department of Civil and Environmental Engineering in Fall 2022. Prior to arriving at the University of Southern California, he spent three years as a Senior Research Engineer at ExxonMobil, where he developed technologies to improve the integrity of wells during construction and operation. Specifically, he worked on composite fluid and solid systems that reduce pressure and stress developments in confined, high-temperature, and high-pressure environments. Before his research experience in industry, he obtained his Ph.D. (2019) on Mechanics of Materials and S.M. (2015) in Civil and Environmental Engineering from the Massachusetts Institute of Technology and received his B.S. (2011) in Civil Engineering with a Minor in Mathematics from North Carolina State University.

Wednesday, December 3, 2025
3:30 PM
Seaver Science Library, Room 202 (SSL 202)

 

host: Plucinsky

Published on August 2nd, 2017Last updated on December 1st, 2025